Hypno - Generation I: Kanto

If you're looking for a Pokémon that focuses on putting others to sleep, you could use Sing with your Jigglypuff or Hypnosis with your Haunter. Alternately, you could use this... whatever it is. Hypno's lemon yellow color scheme, creepy eyes, huge nose, and weird ruffle combine to create the stuff of a child's nightmares.